In the electrolysis of a solution containing both copper sulfate and silver nitrate using inert electrodes, which substance will be deposited first at the cathode?

  1. Copper
  2. Silver
  3. Hydrogen
  4. Oxygen

📝 Detailed explanation

Substances with higher standard reduction potentials are reduced first at the cathode.
The reduction potential of Silver (Ag⁺/Ag) is +0.80V.
The reduction potential of Copper (Cu²⁺/Cu) is +0.34V.
Therefore, Silver will be deposited before Copper.
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