[Olympiad] The solubility product (Ksp) of Calcium sulfate (CaSO₄) is 2.4 × 10⁻⁵. What is the molar solubility of CaSO₄ in a 0.01 M solution of Na₂SO₄?

  1. 2.4 × 10⁻³ M
  2. 4.9 × 10⁻³ M
  3. 2.4 × 10⁻² M
  4. 1.2 × 10⁻³ M

📝 Detailed explanation

CaSO₄(s) ⇌ Ca²⁺ + SO₄²⁻. Let solubility be 's'.
[Ca²⁺] = s, [SO₄²⁻] = 0.01 + s ≈ 0.01.
Ksp = s * 0.01 = 2.4 × 10⁻⁵ -> s = 2.4 × 10⁻³ M.
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