A mixture of butane and propane has a density of 2.321 g/l at STP. Determine the mass fraction (%) of butane in the mixture.

  1. 25%
  2. 60%
  3. 40%
  4. 75%

📝 Batafsil tushuntirish

Molar mass of mixture = 2.321 × 22.4 = 52 g/mol.
M(Butane) = 58, M(Propane) = 44.
Let x be the mole fraction of butane.
58x + 44(1 - x) = 52.
14x = 8, so x = 8 / 14 = 4 / 7.
Mass butane = (4/7) × 58 = 33.14.
Mass propane = (3/7) × 44 = 18.86.
Mass fraction = 33.14 / 52 ≈ 0.637.
Checking 60%: if x=0.5, M=51. If x=0.6, M=52.4. 60% is close.
24 / 30 (80%)
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