Calculate the volume of 0.5 M KMnO₄ required to oxidize 0.2 mol of KNO₂ to KNO₃ in an acidic medium.

  1. 40 ml
  2. 80 ml
  3. 160 ml
  4. 200 ml

📝 Detailed explanation

2KMnO₄ + 5KNO₂ + 3H₂SO₄ → 2MnSO₄ + 5KNO₃ + K₂SO₄ + 3H₂O
Molar ratio KMnO₄ : KNO₂ is 2 : 5.
Moles KMnO₄ = 0.2 × (2 / 5) = 0.08 mol.
Volume = 0.08 / 0.5 = 0.16 L = 160 ml.
Wait, calculation: 0.2 / 2.5 = 0.08. 0.08/0.5 = 0.16. Correct is 160 ml.
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